Abstract

Herein, we report the synthesis of unsymmetrical BODIPY dyads through the reaction of phenol oxygen on BODIPYs with α-carbon atoms on bromoBODIPYs. Excited state interactions were observed for the dyads composed of components having similar absorption wavelengths. When dissimilar components were used to construct the dyad, exciton coupling disappeared and an energy transfer causing a large pseudo-Stokes shift was observed. The reported structures are the first examples of oxygen-bridged unsymmetrical BODIPY-BODIPY dyads.

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