Abstract

Abstract The emission spectra of poly-3-vinylpyrene (PVPy), poly-3-pyrenylmethylvinylether (PPMVE), and poly-9-vinylacridine (PVAc) in solution were measured at room, dry-ice, and liq. N2 temperatures. New observations of excimer fluorescences of these polymers could be obtained. Lifetimes of excimer fluorescences were measured in pulse method with excitation of N2 gas laser; 160, 66, and 31 nsec for PVPy, PPMVE, and PVAc, respectively. Emission spectra of PVPy and PVAc almost exclusively consist of excimer fluorescences even at dry-ice temperature on the contrary to PPMVE.

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