Abstract
1. A study has been made of exchange reactions involving the (C6H5)3C, (C6H5)3Ge, and organometallic derivatives of the thiophenols. 2. The (C6H5)3C and (C6H5)3Ge groups of the thiophenol derivatives are less inclined to intramolecular exchange than are the C6H5Hg, (C6H5)3Sn, and (C6H5)3Pb groups. 3. The geometrical conditions imposed in nonvalence interaction with the o-CH3 group are more restrictive for the (C6H5)3CS and (C6H5)3GeS groups than for C6H5HgS, (C6H5)3SnS, and (C6H5)3PbS. 4. Intramolecular coordination bonding could not be detected in triphenyltin o-chlorothiophenolate, at least within the sensitivity of the methods used here for studying exchange equilibria.
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