Abstract
The kinetics of exchange of18O-containing molecular oxygen with the oxygen of an Al2(MoO4)3 catalyst has been studied in the temperature range 579–680 °C at\(P_{O_2 } = 10\) Torr. The activation energy of exchange is 57 kcal/mol, and the specific rate of exchange varies between 0.79×1011 and 21.2×1011 molec. cm−2 sec−1. Assumptions are made concerning the activity and selectivity of Al2(MoO4)3 with respect to oxidation reactions.
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