Abstract
Abstract We examine kinetic and potential exchange in 1:1 ion-radical complexes of ferrocene (Fc) and π-acceptors like tetracyanoethylene (TCNE). Spin-orbit and asymmetry split the (e2g)3 configuration of Fc+ and lead to anisotropic magnetic moments. The partly-filled Fc+ and TCNE− orbitals are almost orthogonal and suggest alternative charge-transfer processes involving the acceptor and ligands.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
