Abstract
The reaction of CuCl2·2H2O (or CuBr2) with benzoic acid and 1,4,7-trimethyl-1,4,7-triazacyclononane in CH3OH affords green crystals of [{LCuIICl}2(μ-benzoato)](ClO4) (1) or its bromo analog (2). The dinuclear mono(carboxylato)-bridged cations display weak intramolecular antiferromagnetic exchange coupling. An apparent linear magneto−structural correlation between the ratio J/n (J is the coupling constant and n is the number of syn,syn-carboxyalto bridges present) and the Cu−O−C angle α has been found.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
