Abstract

SrFe12O19/Fe-Co core/shell particles with different shell thickness were synthesized by polyol reduction of Fe and Co ions at 180°C with SrFe12O19 particles dispersed in solvent. The core/shell structure is formed by magnetic self-assembly due to the remanent magnetization of SrFe12O19 particles. Within a limited concentration range, the shell thickness could be controlled by regulating the concentration of Fe and Co ions. Core/shell structured SrFe12O19/Fe-Co particles showed more effective exchange coupling effects between hard and soft phases than physically mixed SrFe12O19 and Fe-Co particles.

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