Abstract

The electrochemical behavior of zinc(II) dithiocarbamate complexes (Zn(RR'dtc) 2 ) has been investigated at both platinum and mercury electrodes and compared with that of the analogous cadmium complexes (Cd(RR'dtc) 2 ). Reduction processes for Zn(RR'dtc) 2 are less affected by the choice of electrode material than are the oxidation processes. At both platinum and mercury electrodes, the major reduction process occurs at very negative potentials and yields elemental zinc or zinc amalgam, respectively, and free dithiocarbamate

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