Abstract
The excess volumes of carbon tetrachloride + ethanol, + n-propanol, + i-propanol, + n-butanol, + i-butanol, and + t-butanol have been determined dilatometrically at 308 K. The curves of excess volume against mole fraction are sigmoid for all the normal alcohols, with positive excess volumes in the region rich in carbon tetrachloride and negative excess volumes in the region rich in alcohol. When the alkyl group in the alcohol becomes more branched the negative part of the curve diminishes and in the case of tertiary butanol the curve is everywhere positive.
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