Abstract
Excess volumes of mixing were measured at 20 C for mixtures of four aromatic hydrocarbons (benzene, toluene, ethylbenzene, and p-xylene) with five alkyl acetates (methyl, ethyl, propyl, butyl, and amyl acetates) and two ketones (acetone and 2-butanone). The whole composition range was studied for all 28 binary systems. Specific interactions between the carbonyl and aromatic systems lead to rather small excess volumes, frequently even negative ones. Ketones interact more strongly than alkyl acetates
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