Abstract

Over the complete composition range of mole fractions, densities and ultrasonic velocities of binary liquid mixtures of dimethyl malonate with o-xylene, p-xylene and m-xylene were investigated at 303.15-318.15 K. These parameters were chosen to investigate the  impact of substituents and specific locations on several thermodynamic characteristics of binary mixtures. The deviation in adiabatic  compressibility (∆βad), excess molar volume (VE) and excess intermolecular free length (LfE) were estimated using the experimental measurements. These extraneous parameters are fitted to a polynomial equation of the Redlich-Kister type. Along with the obtained parameter values, the standard deviation (σ) was also determined.

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