Abstract
Isothermal vapour-liquid equilibrium (VLE) data for the ((toluene + pyridine)) system has been measured at four temperatures from approximately 343 K to 383 K, using a dynamic-analytic apparatus. The densities of ((toluene + pyridine)) mixtures were also measured from 298 K to 363 K using an Anton Paar DMA-5000 densitometer. The vapour-liquid phase equilibrium data were modelled by the γ-Φ approach and the Non-Random Two-Liquid and UNIQUAC activity coefficient models. The consistency of the experimental isothermal VLE data were checked by the area and point tests. The experimental density data were modelled using an 8-parameter empirical correlation which allowed for the simultaneous representation of temperature and liquid composition. The experimental data were used to determine the excess properties for volume, Gibbs energy, enthalpy and entropy. The excess volume was modelled using Redlich-Kister polynomials.
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