Excess molar volumes, viscosities, and refractive indices for binary and ternary mixtures of {cyclohexanone (1) + N,N-dimethylacetamide (2) + N,N-diethylethanolamine (3)} at (298.15, 308.15, and 318.15) K

Abstract

Densities ρ, viscosities η, and refractive indices n D, of the binary and ternary mixtures formed by cyclohexanone + N,N-dimethylacetamide + N,N-diethylethanolamine were measured at (298.15, 308.15, and 318.15) K for the liquid region and at ambient pressure for the whole composition ranges. The excess molar volumes V m E, viscosity deviations Δ η, and refractive index deviations Δ n D, were calculated from experimental densities and refractive indices. The excess molar volumes are positive over the mole fraction range for binary mixtures of cyclohexanone(1) + N,N-dimethylacetamide (2) and N,N-dimethylactamide (2) + N,N-diethylethanolamine (3) and increase with increasing temperatures from (298.15 to 318.15) K. The excess molar volumes of cyclohexanone (1) + N,N-diethylethanolamine (3) are S-shaped dependence on composition with negative values in the N,N-diethylethanolamine rich-region and positive values at the opposite extreme and increase with increasing temperatures from (298.15 to 318.15) K. The excess molar volumes are positive over the whole mole fraction ranges for the ternary mixtures at all temperatures. Viscosity deviations are negative over the mole fraction range for all binary and ternary mixtures and decrease with increasing temperatures from (298.15 to 318.15) K. Refractive index deviations are negative over the mole fraction range for all binary and ternary mixtures and increase with increasing temperatures from (298.15 to 318.15) K. The experimental data of constitute were correlated as a function of the mole fraction by using the Redlich–Kister equation for binary and , Cibulka, Jasinski and Malanowski , Singe et al., Pintos et al., Calvo et al., Kohler, and Jacob–Fitzner for ternary mixture, respectively. McAllister 's three body, Hind, and Nissan–Grunberg models were used for correlating the kinematic and dynamic viscosity of binary mixtures. The experimental data of the constitute binaries are analyzed to discuss the nature and strength of intermolecular interactions in these mixtures.