Abstract
The present paper reports the experimental data for density ρ, viscosity η, and speed of sound u in (phenylacetonitrile + 1,2-dichloroethane), (phenylacetonitrile + 1,1,2-trichloroethane), (phenylacetonitrile + 1,1,2,2-tetrachloroethane), (phenylacetonitrile + trichloroethene), and (phenylacetonitrile + tetrachloroethene) over the entire range of composition at T = (303.15 to 313.15) K. These values have been used to calculate the excess molar volumes VE and deviation in isentropic compressibility Δκs. The excess molar volumes and deviation in isentropic compressibility are fitted to a Redlich−Kister-type equation to derive binary coefficients and standard deviation and to elicit the specific interactions like complex formation as well as the saturation of chlorine atoms with π electrons.
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