Abstract
Excess molar enthalpies HE were measured using a microcalorimeter for binary liquid mixtures of dibromomethane (CH2Br2) + cyclohexanone, and dichloromethane (CH2Cl2) + cyclohexanone or + pyrrolidin-2-one at T= 303.15 K. The values of HE are negative for all systems. The excess partial molar enthalpies of the components HEm,1 and HEm,2 were calculated from HE data. The results were interpreted in terms of specific interactions.
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