Abstract

Molar excess enthalpies H e m and molar excess volumes V e m have been determined using a Thermometric flow calorimeter and a Paar DMA 601 density meter, respectively. The measurements were made over the whole composition range for mixtures of 1-hexene, 1-heptene and 1-octene with 1-propanol and 2-propanol at 298.15 K. The results were compared with H e m and V e m values for binary mixtures of a 1-alkene with methanol and ethanol, and of an n-alkane with an alkanol, in order to determine the effect of the double bond in the 1-alkene on the measured properties.

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