Abstract
Excess molar enthalpies, , and excess molar volumes, , of dimethyl carbonate + 1-butanol, + 2-butanol, + 2-methyl-1-butanol, and + 2-methyl-2-butanol have been determined at (288.15, 298.15, and 313.15) K and atmospheric pressure using a flow microcalorimeter and a digital density meter. Excess properties are positive over the entire experimental conditions, increasing as the temperature increases. Maxima values of vary from 2100 up to 2900 J·mol-1. Those of vary from 0.57 up to 0.83 cm3·mol-1. Experimental data have been correlated using Redlich−Kister polynomials, and parameters from least-squares analysis have been reported.
Published Version
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