Abstract
Excess heat capacities of mixtures of non-electrolytes were determined from measurements of volumetric heat capacity in a Picker flow calorimeter. A precision of ±0.02 J K −1 mol −1 was achieved for C p E, using a stepwise procedure. Results are reported for the following binary mixtures at 298.15 K: tetrachloromethane + benzene and + cyclohexane, n-heptane + ethanol, + n-propanol, and + toluene, and isooctane + benzene, and + toluene. In most cases our results are in reasonable agreement with results obtained from other types of calorimeters and with values derived from the temperature variation of excess enthalpies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
