Abstract
The excess enthalpies, HE, at 298.15 K for binary mixtures of chloroalkylbenzenes of general formula C6H5-(CH2)s-Cl (with s = 0, 1, 2, 3) + alkylbenzenes of general formula C6H5-(CH2)t-H (with t = 0, 1, 2, 3, 4) have been measured by flow microcalorimetry. All mixtures containing chlorobenzene (s = 0) and the mixtures of 1-chloro-3-phenylpropane + benzene, methylbenzene, and ethylbenzene exhibit negative HE, and the remaining mixtures are endothermic. Data were fitted by the Redlich−Kister equation. Heats of mixing are quite low: the values at equimolar composition are in the range −143.0 J·mol-1 to +323.0 J·mol-1. The values of partial molar excess enthalpies at infinite dilution, , of both components vary from −0.583 kJ·mol-1 to +1.295 kJ·mol-1.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
