Abstract

Bulk FeSe superconductors of the iron-based (IBS) “11” family containing various additions of silver were thoroughly investigated concerning the microstructure using optical microscopy and electron microscopy (TEM and SEM). The measurements of electrical resistivity were performed through the four-point technique in the temperature interval 2–150 K. The Aslamazov–Larkin model was employed to analyze the fluctuation-induced conductivity (FIC) in all acquired measurements. In all studied products, we found that the FIC curves consist of five different regimes of fluctuation, viz. critical region (CR), three-dimensional (3D), two-dimensional (2D), one-dimensional (1D), and shortwave fluctuation (SWF) regimes. The critical current density (), the lower and upper critical magnetic fields ( and ), the coherence length along the c-axis at zero-temperature ((0)), and further parameters were assessed with regards to the silver amount within the products. The analyses discloses a diminution in the resistivity and a great reduction in (0) with Ag addition. The optimal silver doping amount is achieved for 7 wt.%, which yields the best superconducting transition and the greatest value.

Highlights

  • Polycrystalline, iron-based superconductors (IBS) are interesting candidates for several applications of superconductivity at low temperatures [1,2,3]

  • We thoroughly investigate the microstructure of polycrystalline and bulk FeSe samples with the addition of silver and employ the analysis of the excess conductivity or fluctuation-induced conductivity (FIC) to the FeSe-Ag system

  • The microstructure and the fluctuation-induced conductivity were investigated for a series of polycrystalline FeSe superconductors with silver incorporation

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Summary

Introduction

Polycrystalline, iron-based superconductors (IBS) are interesting candidates for several applications of superconductivity at low temperatures [1,2,3]. Even though the iron-based superconductors are materials with relatively low superconducting transition temperatures, Tc , the superconducting properties like the high upper critical fields, Bc2 , are comparable to other HTSc systems, being much better, as for the direct metallic competitor, MgB2. These advantages were already demonstrated for the IBS 122 compounds in the literature [5,13,14,15], but not yet for the 11 system. We thoroughly investigate the microstructure of polycrystalline and bulk FeSe samples with the addition of silver and employ the analysis of the excess conductivity or fluctuation-induced conductivity (FIC) to the FeSe-Ag system

Sample Preparation and Characterization
Resistance Measurements
Excess Conductivity
Microstructure
Resistivity Measurements
FIC Analysis
Conclusions
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