Exceptionally stable nanostructured air electrodes for reversible solid oxide fuel cells via crystallization-assisted infiltration

Abstract

Nanostructures present favorable prospects of manufacturing high-performing air electrodes for reversible solid oxide fuel cells (RSOFCs) with the potential to reduce their operating temperature. Here, we present trichloroacetic acid as an original infiltration agent for the facile nanoengineering of RSOFC electrodes. The new process relies on the thermal decomposition of trichloroacetic acid in water at temperatures above 70 °C, which causes intense CO2 effervescence and crystallizes out the metal ions in the solution as slightly soluble carbonates. Essentially, this allows for the subsequent infiltration step to be performed immediately after drying, as opposed to conventional infiltration, which requires high-temperature calcination after each infiltration step. The anode-supported RSOFC consisting of a nanostructured LaCoO3 air electrode permitted smooth switching between fuel cell and electrolysis cell modes with no evidence of degradation. In addition, the RSOFC presented exceedingly durable performance during accelerated stability tests.