Abstract
The brittleness and flammability of epoxy thermosets (EP) have largely limited their applications. In this work a phosphorus-containing ionic liquid 1-methylimidazolium tributyl phosphate ([Mim]TBP) is designed and synthesized to develop high-performance and flame-retardant epoxy thermosets. [Mim]TBP significantly accelerates the curing and improves the toughness of epoxy thermosets. The tensile toughness, tensile strength, impact strength and flexural strength of samples with 10phr [Mim]TBP increase by 419.7 %, 100.2 %, 71.7 % and 58.3 %, compared with pure EP, respectively. The increased toughness is due to the significant energy dissipation caused by the ionic bonds breaking between Mim and TBP. When the [Mim]TBP content exceeds 10 phr, the limiting oxygen index (LOI) can reach over 30 % and UL-94 test pass the V-0 rating. The peak heat release rate (pHRR), total heat release (THR), total smoke release (TSR) and peak CO production (PCOP) values effectively decrease by 31.5 %, 30.6 %, 48.3 % and 6.3 %, respectively, thanks to the gas and condensed phase mechanisms of the [Mim]TBP. A new strategy was provided for the development of toughness and fire safety performance epoxy thermosets for high-performance industrial applications.
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