Abstract

In this work, the binary blend of poly(ethylene vinyl acetate) (EVA)/poly(e-caprolactone) (PCL) with different compositions were prepared and the shape memory behaviors were evaluated first. Then, carbon nanotubes (CNTs) were introduced into the composition that exhibited relatively better shape memory effect (SME) to prepare the ternary blend composites with electrically actuated SME. The morphologies of the blend and/or blend composites, the crystallization of the component, and the selective location states of CNTs in the blend composites were comparatively investigated. The results demonstrated that the binary EVA/PCL blends exhibit a typical sea–island structure at low PCL content, a quasi-cocontinuous structure at mediate PCL content and then the sea–island structure at high PCL content. Among these binary blends, the EVA/PCL (60/40) sample exhibits relatively better SME with not only high shape fixing ratio but also shape recovery ratio. The presence of the CNTs further induces the changes of morph...

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