Excellent catalytic effect of LaNi5 on hydrogen storage properties for aluminium hydride at mild temperature

Abstract

The catalytic effect of rare-earth hydrogen storage alloy is investigated for dehydrogenation of alane, which shows a significantly reduced onset dehydrogenation temperature (86 °C) with a high-purity hydrogen storage capacity of 8.6 wt% and an improved dehydrogenation kinetics property (6.3 wt% of dehydrogenation at 100 °C within 60 min). The related mechanism is that the catalytic sites on the surface of the hydrogen storage alloy and the hydrogen storage sites of the entire bulk phase of the hydrogen storage reduce the dehydrogenation temperature of AlH3 and improve the dehydrogenation kinetic performance of AlH3. This facile and effective method significantly improves the dehydrogenation of AlH3 and provides a promising strategy for metal hydride modification.