Abstract

Developing conceptual understanding of solubility and dissolution and the relationship to molecular structure, ionic salts’ charges, and enthalpy and entropy, play a significant role in the learning of chemistry. Dissolution and solubility are topics covered in general chemistry, quantitative analysis, biology, and organic chemistry. Alternative conceptions about some of the key chemistry principles can lead to students’ failure in understanding and accepting some of the future concepts. This study aims to examine some of the challenges and alternate conceptions that students face when learning about solubility and its relationship to Lewis structures and the driving force behind dissolution. A survey that consisted of ionic and molecular solubility related problems, short answers, and Likert-Type questions was given to 200 students in order to analyze their understanding of solubility, dissolution, alternate conceptions they possess, challenges they face in learning about the topics, and its relationship to Lewis dot structures and ionic charges. Our data indicates that students struggle with solving solubility and dissolution process related problems and rely on memorization to approach these problems. For ionic compounds, there seems to be a dependency on memorization and rote-learning of solubility rules instead of development of conceptual understanding of charges of ions and their relationship to entropy and enthalpy in the dissolution process. For molecular compounds, it should be noted that students lack mastery of determining molecular shape and its relationship to function but do emphasize the roles of Lewis structure and polarity in solubility. Finally, students do not attribute the combined effects of enthalpy and entropy as the driving forces behind dissolution and show very fragmented and naïve understanding of the concept.

Highlights

  • Learning chemistry is a cumulative process in which every share of information is accumulated based on the prior knowledge (Özmen, 2004)

  • About 85% of participating students had three or more mistakes. This could be attributed to the fact that they rely on memorization of solubility rules and rote learning which is not effective in learning and understanding

  • SO2 SO3 CO2 solubility of ionic compounds. According to this pie chart, we can realize that the largest percentage, 44%, represents the students that stated that memorization of solubility rules plays an important role in their strategy for predicting solubility

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Summary

Introduction

Learning chemistry is a cumulative process in which every share of information is accumulated based on the prior knowledge (Özmen, 2004). Having established alternative conceptions of some fundamental concepts in general chemistry can have a significant effect on understanding some more intricate concepts that will show up in the future chemistry or any other chemistry related classes. There are five factors that contribute to the development of alternative conceptions in students’ minds and those are: teachers, textbooks, students, contexts, and teaching methods (Setowati, Utomo, & Ashadi, 2018). Once such an idea, notion, or opinion is developed it is not easy to remove it and establish a new, accurate one. It is significant to identify the kind of alternative conceptions students have in order to help them understand and apply a particular concept in the most productive way

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