Abstract

Recently groundmass samples of two high-K volcanic rocks (MDO- 31A, 36-I) and a low-K basalt (BB- 6) have been proposed for Quaternary KAr standardization. The ages given by the suppliers are ∼ 250 ka (MDO- 31A), 4 ka ( 36-I) and 450 ka (BB- 6). Sample 36-I could be used as zero-age sample for many purposes. 40 Ar 39 Ar incremental heating measurements reveal no severe distortions for the KAr systematics of the groundmass samples. Therefore they should be suitable for Quaternary KAr age standardization. The BB- 6 basalt standard shows a slightly distorted 40 Ar 39 Ar age spectrum and obviously contains mineral phases with excess 40Ar. These properties restrict the suitability of BB- 6 for KAr standardization to a certain degree. The geochemical biotite standard Mica-Fe showing both varying K and 40Ar concentrations and disturbed 40 Ar 39 Ar patterns should not be used as reference material in KAr chronometry. First K and Ar results on a recently prepared Tertiary biotite (HD-B 1) are presented. Four kg of this pure biotite ( t=25 Ma, K=8.0%, 40Ar ★=7.7 nl g −1 (STP) = 86% of total 40Ar) are provided for distribution to interested laboratories.

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