Abstract

The electronic phase of the metallic polythiazyl, (SN) x , chain has been examined based on the instability problem of the Hartree-Fock solution. It has been shown that neutral and n-type-doped polythiazyl is Hartree-Fock unstable to generate the charge density wave associated with the non-metallic electronic phase but that slightly p-type-doped material could stay in the metallic phase.

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