Abstract

In this work we present a detailed analysis of the extended x-ray absorption fine Structure (EXAFS) spectra at the cobalt K-edge in a series of Co-containing polymers prepared by reaction of the Schiff-base polymer (C 13 H 17 N 3 ) and a CoX 2 salt, where X = NO 3 , ClO 4 , Cl and (SO 4 ) 1/2 . The analysis of EXAFS data has confirmed the formation of polymeric-coordination complexes as materials with a very low crystallinity.

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