Evolution of PAHs in the mobile phase of low-rank coal during medium–low-temperature pyrolysis

Abstract

The generation and release of polycyclic aromatic hydrocarbons (PAHs) during coal pyrolysis have been extensively studied, yet the evolution process of PAHs in the mobile phase is poorly understood. In this study, Yulin (YL) subbituminous coal and its solid products (YL350–700) obtained by pyrolysis at ∼350–700 °C were treated with dichloromethane, and the extracted PAHs were analyzed by gas chromatography and mass spectrometry. The total PAH concentration in the YL350–700 mobile phase was found to increase and then decrease with increasing pyrolysis temperature, and peak in the YL380 sample. The concentrations of alkylated PAHs were found to be the main contributors to the total PAH concentrations among the YL350–700 samples. YL coal was dominated by 4-ring PAHs, while YL350–700 samples were all dominated by 2-ring PAHs (naphthalene and alkylated naphthalenes). Variations in the proportion of 2-ring PAHs and the degree of naphthalene alkylation in YL350–700 indicated that alkylated naphthalenes were the main component of PAHs generated during YL coal pyrolysis at medium–low temperatures. This may suggest that the condensed aromatic units in the macromolecular structure of YL coal mainly consist of low-ring PAHs. Finally, an evolutionary process for PAHs in the mobile phase of YL subbituminous coal during pyrolysis at medium–low temperatures was proposed.