Abstract

In this work surface modification of Zr-based bulk amorphous alloy Zr 55Cu 30Al 10Ni 5 was carried out with pulsed Nd:YAG laser. The as-cast and modified surface of amorphous alloys at different conditions were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) techniques. Phases like Cu 10Zr 7, CuZr 2 and NiZr 2 were identified which result in the enhancement of hardness of the modified alloys surface. It was observed that low laser power and prolonged irradiation time provides large nucleation frequency and limited growth rate which intern produces small spherical particle dispersion homogeneously distributed in an amorphous matrix resulting significant increase in surface hardness.

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