Abstract
We have studied the evolution of atomic structure and electronic band dispersion of oxygen-induced superstructures on the Mo(110) surface by using low-energy electron diffraction, angle-resolved photoemission spectroscopy, and density functional theory. Our experiments show that adsorption of oxygen at an elevated temperature (473 K) gets rid of the mixed-phase coexisting region observed at room temperature and exhibits three distinct superstructures: $p(2\ifmmode\times\else\texttimes\fi{}2$), $p(2\ifmmode\times\else\texttimes\fi{}1$), and $p(2\ifmmode\times\else\texttimes\fi{}6$) phases. Oxygenation of the Mo(110) surface leads to a confinement-induced gaplike opening at the zone center that can be tuned by the overlayer oxygen coverage. The ``hole'' pockets on the Fermi surface of the clean Mo(110) surface are found to persist upon oxygen adsorption with slightly changed volumes, while the ``electron'' pocket does not show any significant shift in momentum with no Fermi surface nesting behavior until saturation oxygen coverages. Apart from the significant modifications to the electronic states of the clean Mo(110) surface, we also observe the formation of new oxygen-induced bands. The evolution of the surface states near ${E}_{F}$ can be attributed to a change in the surface potential, while the evolution of oxygen-induced bands results from the hybridization between O-$2p\phantom{\rule{4pt}{0ex}}({m}_{j}=1/2$) and Mo-$4d$ (${m}_{j}=1/2$) orbitals at the interface. The interlayer separation, bond length, and lateral repulsive interactions between the adatoms are found to play a crucial role in the selective chemisorption of the Mo(110) surface.
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