Evolution of Carbides in Cr–Mo–Si–V Alloy Steel during the Spheroidization Annealing Process

Abstract

The evolution of eutectic carbide and granular pearlite, including secondary carbide and matrix ferrite, in 1.12C–8.1Cr–2.3Mo–1.08Si–0.32V alloy steel under spheroidization annealing is investigated. This procedure can be divided into two stages: austenitization in the range of 780–900 °C for 0.5–5 h and second annealing in the range of 740–780 °C for 3–7 h. The area fraction, size, number per unit area, and sphericity of carbides are analyzed under different annealing processes. The result indicates that the mean diameter of secondary carbides increases and the number of carbides per area decreases with the increase in temperature in two ranges of 780–900 and 740–780 °C. At >860 °C, the secondary carbide sufficiently spheroidizes, the eutectic carbide dissolves at the tip with a larger radius of curvature, and ferrite grains of the matrix are basically equiaxed. It can be found that the austenitizing stage plays a crucial role in nucleation and coarsening of secondary carbides, dissolution and segmentation of eutectic carbides, and recrystallization of matrix ferrite grains. The microhardness of the sample presents a decreasing tendency from fast to slow with the increase of the average diameter of secondary carbides.