Abstract

Extensive computer simulations are performed at room temperature in liquid D 2O modelled in terms of a realistic intermolecular potential, with the purpose of providing a detailed account of the dispersion of longitudinal current correlations in this system. The data support the results of a recent theoretical study, where a preliminary microscopic interpretation of the anomalous dispersion was proposed. A deeper memory-function analysis shows that a combined kinetic and mode-coupling framework can qualitatively account for the basic dynamical features of the phenomenon.

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