Abstract

Tobacco use was widespread amongst the indigenous populations throughout North and South America prior to European contact; however, the geographical and temporal spread of the plant is poorly understood. Organic residue analysis is providing a new source of information on the diffusion of tobacco based on the presence of nicotine extracted from smoking pipes recovered from archaeological contexts. Using gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-high-resolution mass spectrometry (LC-HRMS) we identified nicotine in a Late Archaic (1685-1530 cal B.C) smoking pipe from the Flint River site in Northern Alabama. This evidence suggests the exploitation of tobacco spread into the southeastern North America nearly a millennium earlier than the current hypothesis on the rate of dispersion of tobacco in pre-Columbian North America.

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