Abstract

Further progress in high-performance microelectronic devices relies on the development of novel materials and device architectures. However, the components and designs that are currently in use have reached their physical limits. Intensive research efforts, ranging from device fabrication to performance evaluation, are required to surmount these limitations. In this paper, we demonstrate that the superior bipolar resistive switching characteristics of a CeO2:Gd-based memory device can be manipulated by means of UV radiation, serving as a new degree of freedom. Furthermore, the metal oxide-based (CeO2:Gd) memory device was found to possess electrical and neuromorphic multifunctionalities. To investigate the underlying switching mechanism of the device, its plasticity behaviour was studied by imposing weak programming conditions. In addition, a short-term to long-term memory transition analogous to the forgetting process in the human brain, which is regarded as a key biological synaptic function for information processing and data storage, was realized. Based on a careful examination of the device’s retention behaviour at elevated temperatures, the filamentary nature of switching in such devices can be understood from a new perspective.

Highlights

  • We report the multifunctional phenomena of bipolar non-volatile resistive switching and volatile rectification in a two-terminal CeO2:Gd-based memory device

  • Such phenomena can be achieved through control of the local migration of oxygen ions/vacancies by means of UV irradiation

  • The oxygen ion/vacancy-mediated filamentary switching behaviour was verified by measuring the temperature dependence of the retention failure time

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Summary

Introduction

With a further increase in the applied potential, the increased OB migration towards the anode generates more oxygen vacancies at a proportional concentration. As a result of this migration, conducting filaments consisting of oxygen vacancies grow between two electrodes. In the case of device operation without UV exposure, the relatively low OB concentration is likely to result in a small or weakly conducting filament between the two electrodes.

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