Abstract
La0.65Sr0.35MnO 3-δ (LSMO) films (δ ≈ 0, 0.07, 0.12) were studied by hard x-ray photoelectron spectroscopy. It is found that the Mn 3d valence band states shift to higher binding energies for oxygen-deficient samples, while their overall width decreases as a result of the reduced density of charge carriers. The concurrent disappearance of the well-screened state at the Mn 2p level indicates a decrease in hybridization of the Mn 3d and the doping-induced states. The lack of clear band gap formation for oxygen-deficient LSMO above the metal/insulator transition is compatible not with polaron formation but, rather, with a Mott variable range hopping mechanism, which is also supported by our transport data. The large electron probing depth of hard x-ray photoelectron spectroscopy is crucial for this study because modifications to the electronic structure may occur in the nearsurface region.
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