Abstract
The double-layer capacity of a DME electrode in mixed solutions of fluoride and bifluoride solutions has been studied in order to investigate the nature of the anodic rise. The analysis procedure of Dutkiewicz and Parsons was used to demonstrate the specific adsorption of both the fluoride and bifluoride ion at positive electrode charges. Only minimum amounts of specifically adsorbed fluoride ions can be obtained from experiment, some of which are tabulated for various solution compositions and electrode charges.
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