Abstract
The ytterbium(III) triflate-catalysed reaction of a para-methoxyaniline, ethyl glyoxalate-derived imine, with a series of different dienes has resulted in products which initially suggest the operation of two possible modes of aza-Diels–Alder reaction, however, a more likely explanation is that a common reaction mechanism is operating, involving a stepwise Lewis acid-catalysed process and a common type of zwitterionic ytterbium complex.
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