Abstract
Die Stabilisierung höherer formaler Oxidationsstufen und eine Metall-Metall-Dreifachbindung sind das Ergebnis der Bildung des Ruthenium(III)-Corrol-Homodimers [{Ru(hedmc)}2] 1 (hedmc=2,3,8,12,17,18-Hexaethyl-7,13-dimethylcorrol), die unter aeroben Bedingungen rasch erfolgt. Die Struktur und Elektronenzustände von 1 wurden durch Röntgenbeugung sowie NMR- und ESR-Spektroskopie untersucht.
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