Abstract

Time-reversal symmetry breaking (TRSB) with a Bardeen-Cooper-Schrieffer (BCS) -like superconductivity occurs in a small, but growing number of noncentrosymmetric (NCS) materials, although the mechanism is poorly understood. We present heat capacity, magnetization, resistivity, and muon spin resonance/relaxation ($\mu$SR) measurements on polycrystalline samples of NCS La$_{7}$Pd$_{3}$. Transverse-field $\mu$SR and heat capacity data show La$_{7}$Pd$_{3}$ is a type-II superconductor with a BCS-like gap structure, while zero-field $\mu$SR results provide evidence of TRSB. We discuss the implications of these results for both the La$_{7}X_{3}$ (where $X=$ Ni, Pd, Rh, Ir) group of superconductors and other CS and NCS superconductors for which TRSB has been observed.

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