Abstract
Evidence is presented for the existence of a non-adiabatic reaction channel, namely the abstraction of an oxygen atom from a nitrogen dioxide molecule upon scattering from an aluminium(111) surface. This reaction channel was studied by exposing the sample to an NO2 molecular beam and subsequently analysing the scattered flux using REMPI spectroscopy. In these experiments, a considerable amount of NO emitted from the surface was detected. The emitted NO has a rotational temperature of ca. 260 K that increases only slowly with surface temperature. In summary, these results provide first evidence for the abstraction reaction NO2(g)→NO(g)+O(a) upon NO2/Al(111) scattering, which may arise when two electrons are rapidly transferred to the incoming molecule while it is unfavourably oriented for concurrent adsorption of both fragments.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Applied Physics A: Materials Science & Processing
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
