Abstract
Analysis of the fluorine N.M.R. spectrum of a sample of hexafluorocyclopropane dissolved in p-ethoxybenzylidene-p-n-butylaniline (EBBA) has given the magnitudes and relative signs of three anisotropic and three isotropic coupling constants. The anisotropic couplings 2 T FF and 3 T FF(cis) appear to be entirely dipolar in origin, whereas the value of 3 T FF(trans) can be considered as 86 per cent dipolar, the remaining 14 per cent being attributed to an anisotropy in the electron-coupled spin-spin interaction.
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