Abstract
Abstract Part weakly alkaline natural uranium-containing water contains abundant Ca2+ and (bi)carbonate. Herein, two kinds of materials, namely mesoporous hydrous manganese dioxide (MHMO) and polyacrylonitrile (PAN)/dolomite composites were synthesized and characterized to evaluate their adsorption behaviors of U(VI) from Ca2+ coexisted bicarbonate solution. Characterization results showed that both samples exhibited good structural stability after U(VI) load. MHMO could coordinate U(VI) through the surface –OH sites, whereas an unfavorable U(VI) adsorption onto mineral composites was deduced. Adsorption tests indicated that increasing Ca2+ and (bi)carbonate amounts suppress U(VI) adsorption process, and ∼19.0 mg/g U adsorbed by MHMO could be obtained in solutions with 1 mmol/L [Ca2+], 5 mmol/L [CO3]T, 50 mg/L [U(VI)]initial at pH 8.0. Moreover, a heterogeneous surface chemical adsorption was verified through kinetics and isotherms study. Results from our study should be useful in exploring the adsorption behaviors and mechanisms of U(VI) on selected inorganic and mineral materials from natural uranium-containing water.
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