Evaluation of the Tenti S6 model for hydrocarbon fuels at elevated temperatures using filtered Rayleigh scattering measurements.

Abstract

This Letter targets the assessment of the well-known Tenti S6 model for predicting the Rayleigh-Brillouin scattering (RBS) spectra of select gas-phase hydrocarbon fuels (CH4, C2H2, C2H4, C3H8, and C4H10) over a temperature range of 300 to 700 K. The Tenti S6 model is evaluated by comparing filtered Rayleigh scattering (FRS) measurements to synthetic FRS signals generated from the combination of the Tenti S6 output and an accurate iodine absorption filter model. The experimental and synthetic FRS results agree very well (<3% difference) over the full temperature range for CH4, C2H2, and C2H4, indicating accurate calculation of the RBS spectra. For C3H8 and C4H10, there are some large differences between the experimental and synthetic FRS results which cannot be resolved through tuning of bulk viscosity, internal heat capacity, or inclusion of vibrational degrees of freedom, suggesting the need for detailed measurements of the Rayleigh-Brillouin spectra.