Abstract

AbstractThermodiffusion has an important role in displacements of hydrocarbon reservoir. The ratio of the evaporation energy to the activation energy of viscous flow in pure limits, τpure,k, is of a great importance in estimating the thermodiffusion coefficient for non‐associating fluid mixtures. Several methods may be used to estimate τpure,k which causes different values for thermodiffusion coefficients. A fixed value for τpure,k was considered to predict the thermodiffusion coefficient. In this paper, Abbasi et al.'s [J. Non‐Equilib. Thermodyn. 2010;35:1–14] model and Shukla and Firoozabadi's model have been applied to predict thermodiffusion coefficients for linear chain hydrocarbon binary mixtures. The results show a very good performance of the simple approach in respect to the previous models in estimating thermodiffusion coefficients. © 2011 Canadian Society for Chemical Engineering

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