Evaluation of the performance of Ni/La 2O 3 catalyst prepared from LaNiO 3 perovskite-type oxides for the production of hydrogen through steam reforming and oxidative steam reforming of ethanol

Abstract

This paper studies the performance of LaNiO 3 perovskite-type oxide precursor as a catalyst for both steam reforming and oxidative steam reforming of ethanol. According to results of temperature-programmed desorption of adsorbed ethanol and by carrying out diffuse reflectance infrared Fourier transform spectroscopy analyses of ethanol steam reforming, ethanol decomposes to dehydrogenated species like acetaldehyde and acetyl, which at moderate temperatures, convert to acetate by the addition of hydroxyl groups. Demethanation of acetate occurs at higher temperatures, leading to a steady state coverage of carbonate. Catalyst deactivation occurs from the deposition of carbon on the surface of the catalyst. Both thermogravimetric and scanning electron microscopy analyses of postreaction samples indicate that lower reaction temperatures and lower H 2O/EtOH ratios favor the deposition of filamentous carbon. However, less carbon formation occurs when the H 2O/EtOH ratio is increased. Increasing reaction temperature or including O 2 in the feed suppresses filamentous carbon formation.