Evaluation of the molecular poisoning phenomenon of W sites in ZSM-5 via synchrotron X-ray powder diffraction.

Abstract

The traditional investigation of complex catalyst poisoning phenomena is in the operation level: poisonings commonly attributed to macroscopic coke deposition and particle size change, etc. Here, we demonstrate that high-resolution SXRD can reveal the structure of the organic molecule-active site complex in a 3-D environment, leading to an understanding of the poisoning mechanism at the molecular level.