Evaluation of the elemental pollution status of Jamaican surface sediments using enrichment factor, geoaccumulation index, ecological risk and potential ecological risk index

Abstract

Surficial marine sediments were sampled along the south-east coast and in Discover Bay Jamaica. Total elemental composition was determined for the sediments using three techniques. Total mass fractions of Al, As, Br, Ce, Co, Cr, Cs, Eu, Fe, La, Mn, Sb, Sc, Th, U, V, and Zn were determined using instrumental neutron activation analysis; Cu, Ni, Pb, Sr and Zr using energy dispersive X-ray fluorescence; and Hg using a direct mercury analyser. Potential anthropogenic hotspots were assessed using indices including enrichment factor (EF), geoaccumulation index (Igeo), ecological risk (Er) and potential ecological risk index (Ri). The quality of the sediments was also assessed using the sediment quality guidelines (SQGs). Temperature, pH, salinity, dissolved oxygen and organic carbon content (OC) were determined to assess variation across sample sites. Results indicated moderate to severe ecological risk at sites in Port Royal and Discovery Bay with ecological risk values as high as 381.9.