Evaluation of the effects of Mount Pinatubo aerosol on differential absorption lidar measurements of stratospheric ozone

Abstract

Substantially increased aerosol backscattering and extinction after a major volcanic eruption can lead to errors in differential absorption lidar (DIAL) measurements of stratospheric ozone. Mie calculations, performed for the wavelengths 308 and 353 nm and based on size distributions measured over Laramie, Wyoming (41°), were used to assess size and temporal evolution of these errors. In many situations, neglecting the different aerosol backscattering at the absorption and reference wavelengths can lead to relative errors in the ozone concentration larger than 100% for the 308‐, 353‐nm pair. The error due to neglecting the differential aerosol extinction, however, will rarely exceed 2%. A correction for this differential extinction should only be attempted when high concentrations (>100 cm−3) of small aerosol particles with radii below 0.1 μm are present, e.g., shortly after an eruption. A correction for the differential backscatter can be made by using additional lidar measurements at a second reference wavelength or by having general size distribution information on the aerosol. Possible corrections were tested and will usually reduce the error in the ozone concentration considerably. For the 308‐, 353‐nm pair, both Mie calculations and a comparison with ozone profiles from electrochemical cell sondes show, however, that even after the correction the uncertainty in the ozone concentration within some regions of the strongly enhanced Mt. Pinatubo aerosol layer can still be substantial, of the order of 10–50%. Wavelength separation smaller than 40 nm or use of wavelengths shorter than 300 nm will reduce the error. The best solution seems to be the addition of Raman channels. It avoids the large error due to the differential backscatter term.