Evaluation of the effectiveness of ex-situ stabilization for arsenic and antimony contaminated soil: Short-term and long-term leaching characteristics

Abstract

Ex-situ stabilization for As and Sb co-contaminated soil was conducted through an iron-based stabilizer, PFSC (a mixture of polymerized ferric sulfate (PFS) and hydrated lime (Ca(OH2)) with a dry mass ratio of 2:1). After field aging for one week, the stabilized contaminated soil was subjected to a horizontal vibration leaching test (HJ 557), Wenzel's sequential extraction, and a semi-dynamic leaching test (ANS 16.1). By assessing the cumulative fractions of As and Sb, the observed diffusion coefficients (Dobs) and leachability indices (LX) of metalloids released from the soil specimens were calculated. The PFSC ex-situ stabilization was effective to immobilize metalloids, and the As and Sb leached concentrations of stabilized contaminated soil samples were lower than remediation targets. Nonspecifically bound As and Sb in the stabilized contaminated soil samples decreased from 4.5 – 9.2 % to 1.5–2.5 % and from 2.2 – 5.8 % to 1.1–1.5 %, respectively. The mechanisms controlling the leaching behaviors of As and Sb included wash-off and diffusion and they were changed with the leaching interval. The mean Dobs of As and Sb released from stabilized contaminated soil specimen were 3.46 × 10−12 and 2.99 × 10−13 cm2 s−1, in the which were two orders of magnitude lower than that of untreated contaminated soil specimen. The mean LX of stabilized contaminated soil specimen for As and Sb releases were 11.40 and 12.83, respectively, indicating that the stabilized contaminated soil was acceptable for “controlled utilization”.